Have found this site semi-useful in that past, so I thought I'd give a little back... Have been enthralled by The Apprentice, and its use of music, so here is a list of music from the series. About half I recognised, and half I found out...
Lindbergh Palace Hotel Suite + Look at that Old Grizzly Bear + Scrapping and Yelling, all from Royal Tenenbaums Soundtrack, composed by Mark Mothersbaugh
Belleville Jungle, from The Triplets of Belleville soundtrack, Composed by Ben Charest
Nach Deutschland, from The Bourne Supremacy Soundtrack, Composed by John Powell
Black White X 5, from Thomas Crown Affair soundtrack, composed by Bill Conti (very brief use in the programme, but to lovely effect)
The Gravel Road, The Village soundtrack, composed by James Newton Howard
Montagues and Capulets, Romeo & Juliet Ballet, Prokofiev
... and these are the ones I was looking for for ages:
Weird is Good & Ichi-Ni-San, both from Matchstick Men soundtrack, composed by Hans Zimmer.
There is also a track from the Adaptation soundtrack which is either "The Writer and the Crazy White Man" or "Adaptation (Fatboy Slim remix)", composed by Carter Burwell
hope someone finds this useful, as it took ages to type out!

Dom.